Naomie Harris as "Eve" aka Miss Moneypenny in a scene with Daniel Craig as James Bond.
Whether "Eve" is a code name or Moneypenny's first name is unknown at this point.None of the previous Bond novels or films give her a first name, though a spin-off novel series, The Moneypenny Diaries, does..."Jane".
Moneypenny didn't appear in either of the previous Craig James Bond 007 movies Casino Royale, which rebooted the series from the early days of Bond's spy career before he received his "00" designation and license to kill or Quantum of Solace.
(Note: Moneypenny did appear in both the novel and 1967 movie versions of Casino Royale.)